Ideal and non-ideal binary mixtures
Distillation of non ideal mixtures

Article REF: J2611 V1

Ideal and non-ideal binary mixtures
Distillation of non ideal mixtures

Authors : Vincent GERBAUD, Ivonne RODRIGUEZ-DONIS

Publication date: September 10, 2010, Review date: March 1, 2015 | Lire en français

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2. Ideal and non-ideal binary mixtures

2.1 Ideal binary mix

2.1.1 Properties of an ideal mixture

By definition, an ideal mixture is one in which interactions within the phase concerned are absent. The vapor phase is also referred to as a "perfect gas". The liquid-vapor equilibrium relationship of an ideal liquid-vapor "perfect gas" mixture obeys Raoult's law:

y_{i} = \frac{P_{i}^{0} (T)}{P} x_{i} Loi de Raoult

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Bibliography

(1) - DOHERTY (M.F.), MALONE (M.F.) - Conceptual design of distillation systems. - McGraw Hill, New York (2001).
(2) - STICHLMAIR (J.G.), FAIR (J.R.) - Distillation. Principles and practice. - Wiley-VCH, New York (1998).

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