Article | REF: J2611 V1

Distillation of non ideal mixtures

Authors: Vincent GERBAUD, Ivonne RODRIGUEZ-DONIS

Publication date: September 10, 2010, Review date: March 1, 2015 | Lire en français

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    2. Ideal and non-ideal binary mixtures

    2.1 Ideal binary mix

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    2.1.1 Properties of an ideal mixture

    By definition, an ideal mixture is one in which interactions within the phase concerned are absent. The vapor phase is also referred to as a "perfect gas". The liquid-vapor equilibrium relationship of an ideal liquid-vapor "perfect gas" mixture obeys Raoult's law:

    yi=Pi0(T)Pxi  Loi de Raoult 
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    Ideal and non-ideal binary mixtures