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Biomass valorization is at the heart of the questions concerning energetic resources in the twenty-first century. Regarding humid biomass, gasification in supercritical water is an interesting valorization process as it allows for the production of a valuable energetic gas due to its non-fossil origin. Gasification in supercritical water concerns more specifically very humid biomass. The influence of the principal operating conditions on the nature and conversion yield of this process are detailed and the most important laboratory pilots are presented.
This article proposes to tackle the carbon capture, utilization and storage challenge through an integrated approach, to reach net zero emission objectives and mitigate global warming. In this perspective, a series of CCUS technologies currently operational at the industrial scale are analyzed from techno economic point of view, in order to identify key synergies or issues within the value chain. Eventually, this article explores the current frontiers of knowledge regarding the molecular chemistry of amine absorbents used in post-combustion capture, which paradoxically remains the most mature and deployed capture technology to date.
Artificial intelligence - AI - methods and big data processing are essential in process and product engineering, a complex and interdisciplinary science. Multilinear regression and principal component analysis are already common, but supervised, unsupervised, and combinatorial learning methods are also used, with new approaches constantly emerging. These techniques simplify the development of models and solve complex problems in various sectors: chemistry, food, etc. This article examines AI methods, their relevance, and their applications, while also addressing the challenges of physical interpretability and extrapolation.
Proton Exchange Membrane - PEM - water electrolysis is a promising technology for the production of high-purity hydrogen and oxygen, addressing current energy and environmental challenges. This article presents the underlying theoretical foundations, describes the operation of elementary cells and the role of key components such as electrocatalysts and polymer membranes, and lists the auxiliary equipment required for the proper operation of the machines. The main industrial applications are presented. Achievable performance levels and limitations and prospects for improvement are also analyzed and discussed.
Batch processes produce high value-added compounds in multiproduct and multiobjective facilities. Their efficiency relies on the integrated management of design, planning, and scheduling. This article outlines the specific features of such processes in the pharmaceutical industry (recipes, campaigns, storage, performance criteria). It highlights the complexity of discrete decision-making and presents modular platforms using continuous flow chemistry as a flexible alternative that combines quality with environmental sustainability.
In order to answer to sustainable development challenges, chemical industry must embrace eco-design to reduce its environmental impact while preserving its innovation potential. This article first presents the changes and choices facing the chemical industry that are driving its transformation. It then introduces life cycle assessment - LCA - and its methodological principles. LCA is a tool that provides a holistic evaluation of the environmental impacts of a product or service, thereby guiding industry decisions. The article goes on to illustrate this approach through comparative examples, analyzing the limitations and biases of LCA, and concludes with perspectives on strengthening eco-design.
Chemical catalysis is set to play a major role in the energy transition and, more generally, in the energy of the future. The aim is to selectively convert renewable energy sources into chemical carriers – including renewable hydrogen and e-fuels – to power human activities, while minimizing pollutant and greenhouse gas emissions. After introducing the essential concepts and traditional catalytic processes, this article presents the main catalytic pathways for small-molecule interconversion, thermochemical biomass and waste valorization, and electrochemical energy conversion and storage.
Green extraction of natural products is based on the design of extraction processes that will reduce energy consumption and eliminate petroleum solvents, while ensuring a safe, high-quality extract. This concept helps meet the challenges of the 21st century for protecting both our environment and consumers, while at the same time making industry more competitive. This article presents the definition and principles of green extraction with applications in agrifood sectors, cosmetics and perfumery, biofuels and fine chemicals.
Synthesis of microcapsules capable of encapsulating water-soluble payloads is of interest for cosmetic and pharmacological applications, but also for the production of artificial cells. There are a lot of methods available to produce such capsules; however, the main problem is to encapsulate payloads within them. In this article, several methods for synthesizing such microcapsules and why it remains difficult to encapsulate materials within them are commented. Finally, an emerging method to fabricate microcapsules is discussed; it consists of using all-in-water emulsions that can spontaneously encapsulate payloads.
The ammonia synthesis, 180 Mt/year, accounts for 2% of global energy consumption and 1.6% of CO2 emissions. Decarbonizing this production by the use of green hydrogen requires evolution of the current Haber-Bosch process towards small units, adapted to the intermittency of renewable energies and operating under moderate synthesis conditions, e.g. T=300-350°C and P=10-50 bar. It induces the development of new catalytic systems. This article provides an overview of recent developments in catalytic materials. Some of them could also be suitable for the ammonia synthesis with innovative processes, such as the "chemical looping" which overcomes certain thermodynamic limitations.
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