Article | REF: J2612 V1

Distillation of non-ideal mixtures

Authors: Vincent GERBAUD, Ivonne RODRIGUEZ-DONIS

Publication date: September 10, 2010, Review date: March 1, 2015 | Lire en français

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    5. Extractive distillation

    The term extractive distillation is reserved for the process where the entrainer E is fed continuously to a given location in the column (boiler, intermediate tray or overhead tray) other than that of the A-B mixture.

    The addition of E amplifies the difference in volatility between constituents, and thus accentuates the driving force of separation. It can even reverse the relative volatilities, so that the normally less volatile component (B by convention) can follow the path of the lighter components.

    In contrast to azeotropic distillation in a rectifying (respectively stripping) column, where the distillate (respectively bottom distillate) is an unstable (respectively stable) node with the lowest (respectively highest) boiling point in the distillation region, extractive distillation produces a pure...

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