Article | REF: K484 V1

Effects of high and very high pressure

Author: Bernard LE NEINDRE

Publication date: December 10, 1990 | Lire en français

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    1. Properties of ultra-high-pressure fluids

    1.1 Compressibility of fluids

    Several quantities can be defined to characterize gas compression. Here are a few of them.

    Compressibility pV is the product of pressure p and volume V, and the virial coefficients are the coefficients in the limited expansion of pV as a function of the inverse of volume or pressure. The development as a function of 1/V is the more fundamental of the two:

    pV = RT [1 + (B (v ) /V ) + (C (v ) /V 2 ) + ...]

    For low-density gases (whose molar volume is greater than the critical...

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