4. Free volume model

A model widely used to describe the viscosity behavior of many low-molar mass liquids was proposed by Eyring et al. . It leads to an Arrhenius-type equation: $η = A exp (\frac{B}{T})$

Another model based on free volume considers a liquid of hard spheres in which diffusion is possible when a vacant volume, larger than...

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Free volume model

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References

(1) - LUCAS (K.) - Chem. Ing. Tech., 53, 959 (1981).
(2) - KASHIWAGI (H.), MAKITA (T.) - Intern. J. Thermophys., 3, 289 (1982).
(3) - KANTI (M.), ZHOU (H.), YE (S.), BONED (C.), LAGOURETTE (B.), SAINT-GUIRONS (H.), XANS (P.),...

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