Principle
Differential scanning calorimetry with modulated temperature (TMDSC)

Article REF: P1206 V1

Principle
Differential scanning calorimetry with modulated temperature (TMDSC)

Authors : Jean GRENET, Bernard LEGENDRE

Publication date: March 10, 2011, Review date: September 13, 2019 | Lire en français

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1. Principle

Introduced some fifteen years ago thanks to the work of M. Reading, differential temperature calorimetry or DSC-TM (MDSC ^® , MT-DSC ^® ) can be regarded as the evolved form of periodic calorimetry. The fundamental aim of Reading and his colleagues was to separate the temperature-dependent contribution to sample response from that dependent on the rate of temperature change:

\frac{d Q}{d t} = C_{p} \frac{d T}{d t} + f (t, T)

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Bibliography

(1) - SCHAWE (J.E.K.), HÜTTER (T.), HEITZ (C.), ALIG (I.), LELLINGER (D.) - Stochastic temperature modulation : a new technique in temperature-modulated DSC. - Thermochimica Acta., 446, p. 147-155 (2006).
(2) - SCHUBNELL (M.), HEITZ (C.), HÜTTER (T.), SCHAWE (J.E.K.) -...

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