4. Crystallographic structures
The crystal structures of representative alkali and alkaline-earth alanates are listed in Table 1 . Although tetra-alanates crystallize in different structures, they share many common properties. As an example, the crystallographic structure of sodium alanate is shown in figure 1 .
Tetra-alanates (M n+ (AlH 4 ) n ) consist of almost perfect tetrahedra of the [AlH 4 ] complex – interconnected by M + ...
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Crystallographic structures
Reaction path for the thermal decomposition of alanates
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