Oxidation and reduction applied to water treatment - Oxygen, chlorine and derived products

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Oxidation and reduction applied to water treatment - Oxygen, chlorine and derived products

Authors : Sylvie BAIG, Pierre MOUCHET

Review date: September 2, 2020 | Lire en français

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Overview

ABSTRACT

Every domain of water treatment, be it preparation or purification, use oxydoreduction techniques. This article presents the most traditional oxidants: oxygen (mostly atmospheric) the feeblest oxidant used by introduction into water; choline and its derived products (hypochlorites, chloramines, chloride dioxide) whose principal application is disinfection. They each have their own characteristics, properties and also limitations in both preparation and use. Oxidants involving techniques that are still being developed are not presented in this article.

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AUTHORS

  • Sylvie BAIG : Chemical engineer ENSIACET - Doctorate in agroresources science from INP Toulouse - Scientific innovation manager at Degrémont

  • Pierre MOUCHET : Agricultural engineer INA Paris-GREF - Former director at Degrémont

 INTRODUCTION

The objectives of the various articles making up this dossier are set out in the introduction to the first article. , which was devoted to the general principles governing redox phenomena and processes in their application to water treatment: overview of fields of use, reminder of definitions and chemical bases, graphic representations (potential-pH and pe-pH diagrams), principles for classifying oxidizers and reducers according to their potency.

This article presents the most traditional oxidizers: oxygen (atmospheric or industrial), chlorine and its derivatives (hypochlorites, chloramines, chlorine dioxide). The third article presents the other oxidants, in particular those involving technologies that are still in constant progress (ozone, "advanced oxidation" processes), as well as the main reducing agents. Practical applications in various water treatments will be the subject of a fourth and final article.

Note: a table of symbols and abbreviations is given at the end of the article.

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