2. Chromatographic properties of carbon dioxide-based mobile phases
2.1 Thermodynamic aspect
As in CPL, retention depends on solute-stationary phase, solute-supercritical fluid and supercritical fluid-stationary phase interactions. Solute-supercritical CO2 interactions can be governed by varying its pressure and, hence, its density (figure 6)
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Chromatographic properties of carbon dioxide-based mobile phases
Columns and stationary phases
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