2. Chromatographic properties of carbon dioxide-based mobile phases
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2.1.1 Influence of density
As in CPL, retention depends on solute-stationary phase, solute-supercritical fluid and supercritical fluid-stationary phase interactions. Solute-supercritical CO
2
interactions can be governed by varying its pressure and, hence, its density (figure
6
)
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Chromatographic properties of carbon dioxide-based mobile phases
Bibliography
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(1) - KLESPER (E.), CORWIN (A.H.), TURNER (D.A.) -
High pressure gas chromatography above critical temperatures.
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J. Org. Chem., 27, p. 700 (1962).
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(2) - SMITH (R.M.) -
Supercritical chromatography.
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