5. Electrolytes and passivation layers
Electrolyte is a medium that enables movement of lithium ions
between negative and positive electrode materials. The performance
of a LiB can be influenced by the nature of electrolyte and its physicochemical
and electrochemical properties. Most common li-quid electrolytes used
in lithium-ion batteries are composed of a lithium salt, one or more
non-aqueous, aprotic organic solvent, and additives. There are several
important specifications for salt and solvent. The lithium salts should
contain monovalent anions that exhibit a high dissociation degree
and moderate size to ensure high mobility. The electrolyte should
be chemically stable and non-corrosive with respect to the current
collectors, have low reactivity towards the battery components, low
toxicity and high safety. The electrolyte formulation depends on the
type of positive and negative electrode materials, as well as on the
specific...
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Electrolytes and passivation layers