1. Working principle of batteries
The working principle of secondary batteries is based on a controlled
and reversible reaction occurring between two electrode materials
that are separated by an electrolyte. This reaction is an oxidation-reduction
reaction, in which the two electrodes exchange charges: negatively-charged
electrons flow through an external electrical circuit from one electrode
to the other, while positively-charged ions move through the electrolyte
inside the battery cell. The direction of charge flow is from the
negative electrode to the positive electrode on discharge, and vice
versa on recharge.
Nota:
in batteries, while electrodes interchange roles between cathode
and anode, conventionally, the positive electrode is referred to as
the “cathode” and the negative electrode as the “anode”, based on
their discharge functions.
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Working principle of batteries