Quantum physics for molecular spectroscopy
Separation and contraction of variables in molecular spectroscopy

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Quantum physics for molecular spectroscopy


Separation and contraction of variables in molecular spectroscopy

Author : Patrick CASSAM-CHENAÏ

Publication date: April 10, 2014, Review date: April 26, 2021 | Lire en français

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1. Quantum physics for molecular spectroscopy

Our understanding of the physical world is based on its partition into that which is subject to change, which we'll generically call "particles", and that which remains invariable, which we'll call "laws".

1.1 Particles of a molecular system

Of all the particles known to contemporary physics, we're going to focus on electrons, currently regarded as elementary particles, and atomic nuclei, which are composite particles made up of nucleons (protons and neutrons), themselves composed of quarks. We define a molecule as a linked system of electrons and at least two nuclei.

We'll omit the photons, i.e. the particles associated with the quantization of the electromagnetic field, at the origin of the coulombic force exerted between charged particles....

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