16-electron environment
Organometallic chemistry - Oxidizing addition

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AF6504 V1 Article

16-electron environment


Organometallic chemistry - Oxidizing addition

Author : Yves JEANNIN

Publication date: October 10, 2000, Review date: March 30, 2015 | Lire en français

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1. 16-electron environment

In the light of Delépine's work on iridium chemistry, the following iridium(I) compound can be prepared by redox, with ethanol as the reducing agent and iridium(III) as the oxidizing agent:

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Carbon monoxide comes from the ethanol used as a solvent. This complex is square planar. It corresponds to an iridium atom surrounded by 16 electrons....

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