Intramolecular oxidative addition
Organometallic chemistry - Oxidizing addition

Article REF: AF6504 V1

Intramolecular oxidative addition
Organometallic chemistry - Oxidizing addition

Author : Yves JEANNIN

Publication date: October 10, 2000, Review date: March 30, 2015 | Lire en français

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4. Intramolecular oxidative addition

The oxidative addition may well be intramolecular, particularly when the 16-electron environment arises following the departure of a ligand. We have already seen the sequence of reactions $[{Fe}_{2} {(CO)}_{4} {(C_{5} H_{5})}_{2}]$ forms from [Fe(CO) ₅ ] and C ₅ H ₆ (cf. article of this treatise). The step described in figure...