2. Polymers and the barrier effect
Barrier polymers are in a semi-crystalline state, so the crystalline phase can be considered impermeable.
Interesting barrier properties are obtained when the permeable (amorphous) structure has a high cohesive density linked to its chemical nature and a low fraction of free volume, particularly with regard to the material's history and thermal characteristics.
2.1 Barrier polymers
These materials, and their shaping, are described in other articles in Techniques de l'Ingénieur
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Polymers and the barrier effect
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