Carbonylation of halides
Carbonylations
Article REF: J5780 V2
Carbonylation of halides
Carbonylations

Author : Pascal MÉTIVIER

Publication date: March 10, 2001 | Lire en français

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5. Carbonylation of halides

5.1 Malonate synthesis

An alkyl chloroacetate is carbonylated very selectively in excellent yield (98%) to malonate using a cobalt-based catalyst between 60 and 80 ˚C under a pressure of 5 to 25 bar .

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