2. Chlorine chlorination

The use of chlorine as a chlorinating agent is the most widely used technique.

Chlorinated aliphatic compounds are formed by reaction:

or substitution of a radical and, more generally, of a hydrogen atom bonded to the carbon atom, with underproduction of hydrochloric acid in the latter case: $— \begin{matrix} | \\ CH \\ | \end{matrix} + {Cl}_{2} \to — \begin{matrix} | \\ CCl \\ | \end{matrix} + HCl$

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Chlorine chlorination

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References

(1) - PIECK (R.), JUNGERS (J.C.) - Réactivité des substances organiques en chloration photochimique. - Bull. Soc. Chim. Belg., 60, p. 357-81 (1951).
(2) - SCHWAB (G.M.), HEYDE (U.) - (Photochloration de CHCl ₃ ). Z. Phys. Chem....

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