3. Hydrochloric acid chlorination

3.1 Reactions with alcohols, ethers, aldehydes

The reaction of alcohols with HCl leads to the corresponding alkyl chlorides via oxonium chlorides: $R—OH + HCl \to {[R—O \begin{matrix} ∕ \\ ∖ \end{matrix} \begin{matrix} H \\ H \end{matrix}]}^{+} {Cl}^{-} \to {RCl + H}_{2} O$
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Hydrochloric acid chlorination

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(1) - PIECK (R.), JUNGERS (J.C.) - Réactivité des substances organiques en chloration photochimique. - Bull. Soc. Chim. Belg., 60, p. 357-81 (1951).
(2) - SCHWAB (G.M.), HEYDE (U.) - (Photochloration de CHCl ₃ ). Z. Phys. Chem....

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