Continuous flow organometallic reactions
Organometallic Flow Chemistry

Article REF: J8030 V1

Continuous flow organometallic reactions
Organometallic Flow Chemistry

Authors : Paul KNOCHEL, Niels WEIDMANN, Maximilian GANIEK, Johannes HARENBERG, Benjamin HEINZ, Alexandre DESAINTJEAN

Publication date: June 10, 2019 | Lire en français

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2. Continuous flow organometallic reactions

2.1 Continuous flow metallization

Using solutions of TMPMgCl·LICl (16; 1.1 to 1.2 M), in THF tetrahydrofuran, it was possible to metallate numerous pyridines and nitrogenous heterocycles (figure 8 ) .

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Bibliography

(1) - KNOCHEL (P.), MILLOT (N.), RODRIGUEZ (A.L.), TUCKER (C.E.) - . – Org. React. 58, 417-731 (2001).
(2) - BOUDIER (A.), BROMM (L.O.), LOTZ (M.), KNOCHEL (P.) - . – Angew. Chem., Int. Ed., 39, 4415-4435 (2000).
(3)...

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