Article | REF: J5670 V1

Fluorinations

Author: André LANTZ

Publication date: March 10, 1998 | Lire en français

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    5. Addition of HF or fluorine to double or triple bonds

    The addition of HF to olefinic hydrocarbons (or alkenes) is generally very straightforward and already takes place at low temperatures and in the absence of a catalyst [5] . The addition follows Markovnikov's rule and therefore, with the exception of ethylene, does not lead to products with CCH2F groups. .

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    Addition of HF or fluorine to double or triple bonds