Article | REF: J4806 V1

Thermally activated batteries lithium/iron disulfide

Author: Patrick MASSET

Publication date: September 10, 2008 | Lire en français

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    5. Self-discharge phenomena

    Self-discharge phenomena in thermal batteries have various origins:

    • partial solubility of lithium or lithium-based compounds in the electrolyte (table 8 );

    • thermal decomposition of pyrite in contact with molten electrolyte ;

    • partial solubility of sulfur species (Li 2 S, FeS, FeS 2 ) (figure 11 );

    • formation of a parasitic phase between pyrite and electrolyte (phase J).

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    Self-discharge phenomena