Article | REF: M2372 V1

Germanium-Metallurgy

Authors: Pierre BLAZY, El-Aïd JDID

Publication date: September 10, 2010 | Lire en français

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    1. Physical and chemical properties

    Box 1 summarizes the main stages in germanium production.

    Box 1 – Brief history

    1886 – Germanium is isolated from argyrodite by Clemens Winkler.

    1940-1945 – Use of germanium in radar installations (Sn-Ge diodes).

    1946 – First processes for recovering germanium from zinc metallurgy.

    1948 – Use of germanium in diodes (electronics, television, computers, telephony, special optical lenses, etc.).

    1956 – New germanium purification techniques, production of single crystals, huge need for semiconductors.

    1965 – Use of germanium oxide as a catalyst in the polymerization of Polyethylene Terephthalate (PET) in Japan.

    1970 – Silicon replaces germanium in microelectronics.

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