6. Conclusion
Mercury porosimetry is a particularly interesting technique for characterizing powders and porous materials. Its strong point is that it is a "multi-scale" experiment, enabling pore sizes from a few nanometers to a hundred micrometers to be assessed, which is unique. It's also fast, taking just two hours to characterize a sample in most cases. It is perfectly complementary to gas adsorption methods, which are limited to the micro-meso range. Generally speaking, it gives access to the size distribution of pore entrances.
Disadvantages include waste management, of course, but also a number of scientific issues. These are either specific to mercury, or to the use of a capillary phenomenon, as in the case of gas adsorption. What is specific to mercury is the use of a contact angle, the value of which is generally not directly measurable on the sample under study. We...
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Conclusion
Bibliography
- (1) - THOMMES (M.), KANEKO (K.), NEIMARK (A.V.), OLIVIER (J.P.), RODRIGUEZ-REINOSO (F.), ROUQUEROL (J.S.W.), SING (K.S.W.) - Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution - (IUPAC Technical Report). Pure and Appl. Chem., 87(9-10), p. 1051-1069 (2015).
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Standards and norms
- Assessment of pore size distribution and porosity of solid materials by mercury porosimetry and gas adsorption – Part 1: Mercury porosimetry. - ISO 15901-1 - 2016
Regulations
Mercury toxicological data sheet https://www.inrs.fr/publications/bdd/fichetox/fiche.html?refINRS=FICHETOX_55
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Manufacturers
Anton Paar
Pormaster range https://www.anton-paar.com/fr-fr/produits/details/serie-poremasterr/
Micromeritics
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