Mercury process
Chlorine (Cl2)
Article REF: J6215 V1
Mercury process
Chlorine (Cl2)

Author : Jean-Christophe MILLET

Publication date: September 10, 2007

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2. Mercury process

2.1 Process principle

The basic principle of the mercury process (figure 11 ) is to produce chlorine in the electrolysis cell and soda ash and hydrogen in a separate reactor called the decomposer. At the anode, chlorine is produced by oxidizing chloride.

At the cathode, sodium amalgam is formed in mercury at a content of around 0.2% by mass by reduction of the Na + ion according to the reaction : Na++eHgNaHg

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