General characteristics of hydrogenation
Hydrocarbons hydrogenation

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J5500 V3 Article

General characteristics of hydrogenation


Hydrocarbons hydrogenation

Authors : Cécile THOMAZEAU, Christophe BOYER

Publication date: September 10, 2011, Review date: February 1, 2016 | Lire en français

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1. General characteristics of hydrogenation

1.1 Thermodynamics

All hydrogenations are exothermic reactions . In each family of compounds (Table 1 ), the free enthalpy of hydrogenation decreases slightly as the molecular weight of the hydrocarbons increases.

What's more, the addition of hydrogen to an unsaturated molecule results in a decrease in the entropy of the entire system, so all hydrogenations are balanced reactions. Obtaining saturated molecules is favored by low temperatures and...

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