Article | REF: K535 V2

Thermodynamic constants - Thermodynamic data for fluids

Author: Jean GOSSE

Publication date: June 10, 1990 | Lire en français

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    4. Interaction parameters. Generalization of the law of corresponding states

    4.1 Interaction in a pair of molecules

    Theory relates the physical properties of a fluid to the analysis of the interaction of models . There are various interaction models, the simplest of which involve only two parameters, and among these for non-polar molecules the Lennard-Jones model has proved to be well suited. Recall the Lennard-Jones 12-6 interaction potential: φ=4ε(σr)12(σr)6

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