Interaction parameters. Generalization of the law of corresponding states
Thermodynamic constants - Thermodynamic data for fluids
Article REF: K535 V2
Interaction parameters. Generalization of the law of corresponding states
Thermodynamic constants - Thermodynamic data for fluids

Author : Jean GOSSE

Publication date: June 10, 1990 | Lire en français

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4. Interaction parameters. Generalization of the law of corresponding states

4.1 Interaction in a pair of molecules

Theory relates the physical properties of a fluid to the analysis of the interaction of models . There are various interaction models, the simplest of which involve only two parameters, and among these for non-polar molecules the Lennard-Jones model has proved to be well suited. Recall the Lennard-Jones 12-6 interaction potential: φ=4 ε⌈(σr)12−(σr)6⌉

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