Sources of industrial silver pollution
Silver metallurgy
Article REF: M2396 V1
Sources of industrial silver pollution
Silver metallurgy

Authors : Pierre BLAZY, El-Aïd JDID

Publication date: December 10, 2006 | Lire en français

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13. Sources of industrial silver pollution

In France, the main source of silver pollution is the photographic industry, which is the main user of silver (55% in 1999). Mirror-making and electroplating are the next two major uses.

13.1 Silvering and de-silvering waste (mirrors, electroplating, etc.)

These include silver electrolyte baths, desilvering solutions from the electronics and crafts sectors, and mirror silvering solutions. Reformed cyanide baths and electroplating rinse water must be decyanidized. They must not exceed 0.1 mg/L CN when discharged. Cyanide is destroyed with sodium hypochlorite. Silver is recovered by electrolysis or fixed by resins. A special case is ammoniacal silver solutions used with a reducing agent for silvering mirrors....

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