Quizzed article | REF: M2360 V2

Zirconium and hafnium metallurgy

Author: Pierre BARBERIS

Publication date: February 10, 2016, Review date: December 14, 2021 | Lire en français

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    2. Ingot production

    2.1 Ingot smelting

    As with other reactive or refractory metals, the melting of Zr or Hf and their alloys is dominated by the following features:

    • the very high reactivity of Zr or Hf towards air and most of the other gases already mentioned, which means they have to be melted in a vacuum or in an extremely pure neutral gas;

    • very high melting point: 1850°C for Zr and 2225°C for Hf ;

    • the aggressiveness of molten metal towards crucibles: it reduces or dissolves almost all known refractories, including graphite. At laboratory level, alloy fusions in a Yttrin crucible (Y 2 O 3-x ) have...

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