Article | REF: K825 V1

Electrochemical constants of molten salts

Authors: Jacques BOUTEILLON, Jean-Claude POIGNET

Publication date: May 10, 1996 | Lire en français

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    3. Constants relating to electrode-electrolyte interfaces

    3.1 Electrode potentials

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    3.1.1 Measurement methods

    In molten salt media, the standard potential of an electrode is specific to each solvent, and there are as many potential scales as there are solvents. The reference electrode used depends on the chosen solvent, but the couples Ag(I)/Ag and Cl 2 /Cl , whose behavior is nernstian in most molten salt media, are most often selected as the reference electrode [13]...

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    Constants relating to electrode-electrolyte interfaces
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