3. Substitution of a hydrogen atom
3.1 Elemental fluorine fluorination
As previously mentioned, fluorination of a hydrogenated compound with elemental fluorine is a very violent reaction, difficult to control and not very selective. Numerous methods and techniques designed to improve reaction control have been proposed
dilution of fluorine with an inert gas (nitrogen, etc.);
dilution of the organic product to be fluorinated with an inert solvent;
low-temperature fluorination ;
continuous processes with concentration and temperature gradients.
These fluorinations have...
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Substitution of a hydrogen atom
Preparation of fluorinated products by chlorine-fluorine exchange
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