Mercury process
Chlorine (Cl2)
Article REF: J6215 V2
Mercury process
Chlorine (Cl2)

Author : Jean-Christophe MILLET

Publication date: September 10, 2007 | Lire en français

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2. Mercury process

2.1 Process principle

The basic principle of the mercury process (Figure 11 ) is to produce chlorine in the electrolysis cell and soda and hydrogen in a separate reactor called a decomposer. Thus, chlorine is produced at the anode by oxidation of chloride.

At the cathode, sodium amalgam forms in the mercury at a concentration of approximately 0.2% by mass through the reduction of the Na + ion according to the following reaction: Na++eHgNaHg

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