Carbon monoxide reactions
Coordination catalysis — Part 2

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Carbon monoxide reactions


Coordination catalysis — Part 2

Author : Dominique COMMEREUC

Publication date: December 10, 2003 | Lire en français

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3. Carbon monoxide reactions

They fall into two main groups:

  • reactions of carbon monoxide with itself or with non-carbon co-reactants (hydrogen, water);

  • reactions of carbon monoxide with various carbon substrates (alkenes, dialkenes, oxygenated compounds, nitrogen compounds).

The second group uses a wide variety of coordination complexes as catalysts, and we have adopted a classification based on the nature of the substrate involved.

The first group will be dealt with at the end of this paragraph, because of its lesser importance in coordination catalysis: so-called hydrocondensation reactions are more generally the province of heterogeneous catalysis, due in particular to the high temperatures required for their implementation, which are more often than not incompatible with...

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