Overview
ABSTRACT
The analytical procedures presented in this paper have been designed and developed in research laboratories in order to extract gases, namely the noble gases, trapped in rocks. The extraction methods, always carried out under ultra high vacuum in order to minimize atmospheric contamination, include crushing, fusion (resistive or inductive furnace, laser CO2) or ablation (exciplexe) and depend on the nature of the samples. This article describes the extraction systems and presents their fields of use and their limits.
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Read the articleAUTHORS
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Laurent ZIMMERMANN: Research Engineer, CNRS, Centre de Recherches Pétrographiques et Géochimiques, Vandœuvre-lès-Nancy
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Bernard MARTY: University Professor, CNRS, Centre de Recherches Pétrographiques et Géochimiques, Vandœuvre-lès-Nancy - École nationale supérieure de géologie, Nancy
INTRODUCTION
Rare gases, also known as noble gases, are chemical elements belonging to group "0" of the periodic table. Under normal conditions of temperature and pressure (273 K, 1 atm), they are monoatomic gases with the respective symbols He (Helium), Ne (Neon), Ar (Argon), Kr (Krypton) and Xe (Xenon). Their saturated outer electron layers, with two electrons for He and eight for Ne-Ar-Kr and Xe, give them a special physical characteristic, namely chemical inertia in relation to other elements, and they are therefore considered excellent geochemical tracers. Each noble gas has several isotopes: 2 for helium ( 3 - 4 He); 3 for neon ( 20 - 21 - 22 Ne) and argon ( 36 - 38 - 40 Ar) ; 6 for krypton ( 78 - 80 - 82 - 83 - 84 - 86 Kr) and finally 9 for xenon ( 124 - 126 - 128 - 129 - 130 - 131 - 132 - 134 - 136 Xe), and their isotopic compositions have been constantly evolving since the Earth's accretion, 4.56 billion years ago, through nuclear reactions, whether radiogenic (radioactivity), nucleogenic (nuclear reactions) or cosmogenic (isotope production through interactions with cosmic radiation). The elemental and isotopic compositions of all the Earth's reservoirs of noble gases (atmosphere, crust and surface and deep mantle) have also changed as a result:
degassing ;
to mantle differentiation;
leakage (helium) into space in the upper atmosphere;
human activity since the industrial revolution (radiogenic helium entering the atmosphere from fossil fuels (coal, gas, oil) and tritiogenic helium from nuclear testing in the atmosphere, which generated 3 He by 3 H decay)....
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KEYWORDS
laser | furnace | | crushing |
Ultra-high vacuum extraction methods for rare gases
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