Thermochemical data necessary for heat balances for steel and ironmaking

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M1726 V2 Article

Thermochemical data necessary for heat balances for steel and ironmaking

Author : Jean LEHMANN

Publication date: June 10, 2026 | Lire en français

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Overview

ABSTRACT

This article compiles the numerical values of enthalpy variations, between 25°C and various temperatures, for pure substances, elements, and compounds. It also includes the temperatures and enthalpy variations associated with phase transformations of some of these pure substances. Enthalpy of formation values for compounds at different temperatures are also reported. Secondly, a technique for evaluating the enthalpy of dissolution of elements in pure or low-alloyed liquid iron is presented. Finally, the document also presents data relative to various industrial materials such as steelmaking slags, fuels, coke, and pig iron.

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AUTHOR

  • Jean LEHMANN : Graduate of the École des Mines de Paris, Doctor of Engineering, Doctor of Science - THIRST (formerly Expert ArcelorMittal Global R&D), Metz

 INTRODUCTION

This article provides engineers with all the thermochemical data needed to prepare heat balances in pyrometallurgy, particularly in the steel industry.

Commercial software programs largely rely on the data presented in this article. These programs enable enthalpy calculations in a wide range of situations. However, handling complex cases requires specific training.

To meet the specific needs of the steel industry, § 1 and § 2 cover systems consisting either of pure chemical elements or of stoichiometric compounds that are heated from 25 °C to a temperature t .

§ 3 , § 4

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KEYWORDS

gas   |   enthalpy   |   metal   |   slag   |   oxides   |   dissolution

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Thermochemical data necessary for heat balances for steel and ironmaking

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