Overview
ABSTRACT
This article relates to the treatment operations for the elimination of insoluble - or particulate - substances present in natural fresh water used as raw material in industry and the production of drinking water. All of these operations are generally grouped under the name of “water clarification”. The processes used are purely mechanical and physical (screening, natural decantation and flotation, filtration) or physicochemical (coagulation-flocculation coupled with a liquid-solid separation technique, dissolved air flotation). The operations are explained (theoretically) and described (technologically), with the expected performances and the main malfunctions.
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Read the articleAUTHOR
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Bernard LEGUBE: Professor Emeritus at the École Nationale Supérieure d'Ingénieurs de Poitiers (ENSIP) and the University of Poitiers – CNRS Joint Research Unit "Institut de Chimie des Matériaux et des Milieux de Poitiers (IC2MP), ENSI-Poitiers, Building B1, 1 rue Marcel Doré, TSA 41105, 86073 POITIERS Cedex 9, France
INTRODUCTION
This article only concerns water directly involved in industrial processes through the means available to achieve the required quality objectives when the raw material is natural fresh water, with seawater being subject to specific desalination techniques. In many cases, there are significant similarities with the treatment of drinking water, which is similar to all or part of the treatment of industrial water.
Whether the resource is surface water (river, natural or artificial lake) or groundwater, the raw water it supplies to the user will have all or some of the following undesirable characteristics:
organoleptic criteria: turbidity, color, taste, smell;
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chemical criteria, corresponding to constituents:
are naturally present in water: mineral salts (e.g., hardness, sulfates, chlorides, etc.), iron, manganese, ammonium, fluorides, arsenic, organic matter known as "natural" or MON (particularly humic substances responsible for color), etc.
either caused by pollution: anthropogenic macropollutants (carbon, nitrogen, and phosphorus organic matter, nitrates, phosphates), mineral micropollutants (heavy metals, metalloids, oxohalides), or organic micropollutants (pesticides, hydrocarbons, phenols, detergents, per- and polyfluoroalkyl substances or PFAS, drug residues, etc.);
Biological criteria: these mainly concern pathogenic germs carried by fecal pollution, but also organisms whose natural habitat is water (viruses, protozoa, planktonic microalgae or phytoplankton, microinvertebrates or zooplankton, environmental bacteria).
To eliminate or correct all these unfavorable parameters, water treatment plants have a number of tools at their disposal, which must first be reviewed: coagulation and flocculation reactors; decanters; flotation units; beds of granular materials with filtering, adsorbing, and/or neutralizing effects; adsorption, oxidation, and ion exchange reactors; membrane processes, etc. These tools will be combined in more or less complex processes, depending on the industry in question and the use of the water
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KEYWORDS
flotation | decantation | Coagulation-flocculation | depth filtration
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